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A Convenient Synthetic Method for Trisubstituted s-Triazines

โœ Scribed by Chen, Chen; Dagnino, Raymond; McCarthy, James R.


Book ID
126257816
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
366 KB
Volume
60
Category
Article
ISSN
0022-3263

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A new synthetic route was developed via the nucleophilic addition of lithium alkynylide to 1-arylsulfonyl cyclopropanol 1 to afford 1-alkynyl cyclopropanol, which then reacted with aryl iodide to construct trisubstituted cross-conjugated dienones through a palladiumcatalyzed process, where the key s