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A convenient synthesis of Δ1-pyrrolines and Δ1- piperideines

✍ Scribed by Larry E. Overman; Robert M. Burk

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
89 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

Imines 2 are formed in excellent yield from the reaction of nitriles 2 with diisobutylaluminum hydride.

Cyclic imines such as 2 are useful intermediates for preparing azacyclics that contain pyrrolidine or piperidine rings.

📜 SIMILAR VOLUMES

A convinient synthesis of δ1-pyrolines a
A convinient synthesis of δ1-pyrolines and δ1-piperideines
✍ Larry E. Overman; Robert M. Burk 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 32 KB

The 6th line from the bottom on page 5737:"(THF," should read "(toluene,'. GENERATION AND REACTIONS OF THE LITHIUM ENOLATE OF THE IRON ACETYL COMPLEX Cp(CO)2FeCOCH3, Kerry Brinkman

Synthesis of β-Trifluoromethylated Δ1-Py
Synthesis of β-Trifluoromethylated Δ1-Pyrrolines
✍ Olivier Marrec; Carole Christophe; Thierry Billard; Bernard Langlois; Jean-Pierr 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 204 KB 👁 1 views

## Abstract Trifluoromethylated Δ^1^‐pyrrolines have been easily synthesized in a one‐pot procedure from β‐(trifluoromethyl)enones. These substrates are valuable building blocks for further syntheses. For example, trifluoromethylated prolines have been obtained.