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A Convenient Synthesis of the Monoalkylpyridines; a New Prototropic Reaction of 3-Picoline 1,2

✍ Scribed by Brown, Herbert C.; Murphey, Wilbur A.


Book ID
120000010
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
714 KB
Volume
73
Category
Article
ISSN
0002-7863

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A new enamine reaction: synthesis of 3-a
✍ L. Marchetti; G. Tosi πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 French βš– 215 KB

Cyclohexanone enamines react with dibenzoyldiimide (IIa) at room temperature leading to a I:1 addition product in almost quantitative yield. This adduct, on mild acidic hydrolysis, gives 2-(N,N'-dibenzoyl)hydrazinccyclohexanone (IVa), identical with that obtained from cyclohexanone and (IIa) at lOOa