A Convenient Synthesis of Substituted 2-Phenylnaphthalenes From Phenylacetones
β Scribed by Philippe Cotelle; Jean-Pierre Catteau
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 462 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Treatment of phenylawtones 1 with beron tribromide gives the l,3-dimethyl-2phenylmphtalenes 2 in good yields by a tandem aldnl condensation-intramolecularFriedel-Crafts eyclization.In the eases of methoxyphenylacetonesa dsmethylationoceuts leading to l,3dimetbyl-2hydroxyphenylnaphtols. @ 1997Publishedby Elsevier ScienceLtd.
π SIMILAR VOLUMES
A rapid and convenient synthesis of the 3-trifluoromethanesuifonyloxy-2-pyridone 2, one of the first examples of this class of compound, was achieved by Vilsmeier formylation and cyclisation of the acyl enamine 6. The triflate 2 was found to undergo a range of palladium-catalysed coupling reactions
## Abstract Eleven representatives of 6β__n__βalkoxyβ and 6β__n__βalkanoyloxyβ2β(4β²βcyanophenyl)βnaphthalenes, a new class of nematogens, are described.
## Abstract For Abstract see ChemInform Abstract in Full Text.