๐”– Bobbio Scriptorium
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A Convenient Synthesis of Orthoformic Esters

โœ Scribed by Alexander, Elliot R.; Busch, Hirsh M.


Book ID
126892830
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
262 KB
Volume
74
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


ESTERS OF ORTHOFORMIC ACID
โœ Sah, Peter P. T.; Ma, Tsu Sheng ๐Ÿ“‚ Article ๐Ÿ“… 1932 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 206 KB
Convenient synthesis of .alpha.-keto est
โœ Eliel, Ernest L.; Hartmann, Armando A. ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 260 KB
Convenient synthesis of a reactive ester
โœ Erin DiMauro; Albert J. Fry ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 263 KB

Reaction between methyl 3-phenyl-3-trimethylsilylpropionate (8) and catalytic quantities of tetrabutylammonium triphenyldifluorosilicate (TBAT) effects desilylation to the corresponding homoenolate, which can be trapped by a variety of electrophiles. Rearrangement of the homoenolate to the more stab