A convenient synthesis of O-alkyl thioesters from esters
✍ Scribed by E.J. Corey; Stephen W. Wright
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 84 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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The alkyl o-hydroxyphenyl hydrogen phosphates have been used as intermediates in the synthesis of alkyl dihydrogen phosphates. In this work we report its application in the synthesis of dialkyl hydrogen phosphates. The alkyl o-hydroxyphenyl hydrogen phosphates can be prepared, in good yield,
## Abstract The organoselenium‐induced ring‐closure reaction of __O__‐allyl oximes gave cyclic iminium salts, which reacted with Grignard reagents to produce __N__‐alkyl‐4‐phenylselenoisoxazolidines. 2,5‐Dihydroisoxazoles could be obtained in good yields by subsequent selenoxide __syn__‐elimination