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A Convenient Synthesis of N, N, N'-Trisubstituted Ethylenediamine Derivatives From 2-Methyl-2-imidazoline

โœ Scribed by Xia, Chizhong; Kang, Congmin; Zhao, Bingjun; Chen, Jianxin; Wang, Hongxing; Zhou, Peiwen


Book ID
126521605
Publisher
Taylor and Francis Group
Year
2000
Tongue
English
Weight
280 KB
Volume
30
Category
Article
ISSN
0039-7911

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In a thermal inverse-type hetero-Diels-Alder reaction of O-silyl-protected lactal 1 and bis(2,2,2-trichloroethyl) azodicarboxylate (2), the dihydrooxadiazine derivative 3 was obtained in a very high yield; transesterification with benzyl alcohol furnished the corresponding derivative 4. Treatment of