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A convenient synthesis of methyl 4,6-O-benzylidene-α- and β-D-allopyranosides

✍ Scribed by Yôtaro Kondo


Book ID
108307984
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
263 KB
Volume
30
Category
Article
ISSN
0008-6215

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An alternative synthesis of methyl 2,3-a
✍ Harry W.C. Raaijmakers; Binne Zwanenburg; Gordon J.F. Chittenden 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 583 KB

New simple routes to the title epoxide, using carbonate esters of methyl 4,6-O-benzyiidenea-D-glucopyranoside, are described. Some mechanistic aspects of the reactions are discussed. Sugar epoxides (oxiranes) are of considerable practical importance'-4. They are usually prepared from sulfonic ester