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A convenient synthesis of 4(5)-mono-, 4,5-di-, and 2,4,5-tri-substituted imidazoles

โœ Scribed by Brian Iddon; Nazir Khan

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
222 KB
Volume
27
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A procedure is described for the stepwise introduction of substituents (hydrogen included) into the imidazole ring by FGI of the bromine atoms in l-protected 2,4,5-tribromoimidazoles in the order 2 -f 5 + 4 using halogen-metal exchange techniques.

Despite the considerable industrial importance of imidazoles and a widespread interest in their chemistry many simple imidazoles are not readily accessible.

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