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A Convenient Stereoselective Synthesis of Trifluoromethyl-Substituted Polyfunctionalized Cyclopropane: Synthesis of (.+-.)-trans-Trifluoronorcoronamic Acid.

โœ Scribed by Biao Jiang; Fangjiang Zhang; Wennan Xiong


Publisher
John Wiley and Sons
Year
2003
Weight
161 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract The fluorineโ€containing __trans__โ€1,2โ€cyclopropane derivatives **4ba**โ€“**4dd** were synthesized from the fluorineโ€containing electronโ€deficient alkenes **3a**โ€“**3d** with semistabilized arsonium ylides **2b**โ€“**2d**, in biphasic system of dichloromethaneโ€50% aqueous sodium hydroxide, ge