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A Convenient Road to 1-Chloropentacycloundecanes – A Joint Experimental and Computational Investigation

✍ Scribed by Dmitry I. Sharapa; Alexander V. Gayday; Alena G. Mitlenko; Igor A. Levandovskiy; Tatyana E. Shubina

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
803 KB
Volume
2011
Category
Article
ISSN
1434-193X

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✦ Synopsis

An efficient synthetic strategy to obtain 1-chloro-C s -trishomocubane and 1-chloro-D 3 -trishomocubane is described. 1-Chloro-C s -trishomocubane is synthesized by a regioselective Diels-Alder reaction, and B3PW91/6-31G(d,p) calculations offer a plausible explanation of the reaction mechanism. Surprisingly, 1-chloro-C s -trishomocubane does not undergo

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