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A convenient procedure for the cis-hydroxylation of olefins

✍ Scribed by L. Mangoni; M. Adinolfi; G. Barone; M. Parrilli


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
120 KB
Volume
14
Category
Article
ISSN
0040-4039

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A convenient procedure for the synthesis
✍ Kung K. Wang; Zhongguo Wang πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 332 KB

Bromoboration of l-hexyne with BBr, followed by treatment with 2-propanol produced alkenyl boronic ester 3. Subsequent Pd(O)-catalyzed cross-coupling with acetylenic zinc chlorides and iodination furnished enyne iodides 6, which were then converted to enyne-allenes 8 by a second Pd(O)-catalyzed reac