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A convenient preparation of pentafluorophenyl(fluoro)silanes: reactivity of pentafluorophenyltrifluorosilane

โœ Scribed by H.J. Frohn; M. Giesen; A. Klose; A. Lewin; V.V. Bardin


Book ID
103227710
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
829 KB
Volume
506
Category
Article
ISSN
0022-328X

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a-Fluorophenylacetonitriles (31 are readily prepared by the treatment of the corresponding benzaldehyde cyanohydrin trimethylsilylethers (2) with diethylaminosulfur trifluoride (DASTI. This method for the introduction of fluorine alpha to a cyano group iS also applicable to the cyanohydrin trimethyl