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A Convenient Preparation of N-Alkyl and N-Arylamines by Smiles Rearrangement — Synthesis of Analogues of Diclofenac.

✍ Scribed by M. S. Wadia; D. V. Patil

Publisher
John Wiley and Sons
Year
2003
Weight
82 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract The organoselenium‐induced ring‐closure reaction of __O__‐allyl oximes gave cyclic iminium salts, which reacted with Grignard reagents to produce __N__‐alkyl‐4‐phenylselenoisoxazolidines. 2,5‐Dihydroisoxazoles could be obtained in good yields by subsequent selenoxide __syn__‐elimination