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A Convenient Preparation of Glycosyl Chlorides from Aryl/Alkyl Thioglycosides

โœ Scribed by Sugiyama, Shin; Diakur, James M.


Book ID
126154418
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
46 KB
Volume
2
Category
Article
ISSN
1523-7060

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Recently, we have reported that copper(I) methyltrialkylborates readily undergo addition reactions to acrylonitrile, ethyl acrylate, and 1-acyl-Z-vinylcyclopropane.' These reagents also react with relatively active halides such as benzyl,2 allyl, and propargyl halides. 3 Inan attempt to develop the