Isomeric 2-deoxy aldonolactones undergo Horner-Emmons reactions with 2-[bis(2,2,2-trifluoroethoxy)phosphoryl] 1,3-dithiane, to give the corresponding ketene dithioacetals, which are the key intermediates in the synthesis of 3-deoxy-2-keto-aldonic adds.
β¦ LIBER β¦
A Convenient Modification of the Kiliani Synthesis of Higher Carbon Acids (or their Lactones) from Reducing Sugars 1
β Scribed by Hudson, C. S.; Hartley, Olive; Purves, Clifford B.
- Book ID
- 127373061
- Publisher
- American Chemical Society
- Year
- 1934
- Tongue
- English
- Weight
- 219 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0002-7863
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