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A Convenient Method for the Preparation of 1,3-Cyclohexanedione 1

โœ Scribed by Sircar, J. C.; Meyers, A. I.


Book ID
127346331
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
296 KB
Volume
30
Category
Article
ISSN
0022-3263

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Two methods for the preparation of 2-cyc
โœ Mark E. Fraley; Robert S. Rubino ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 217 KB

The addition of organolithium or Grignard reagents to vinylogous ester resin l followed by mild hydrolysis of product resins 2 provides 3-alkyl-2-cyclohexenones in high purity (>95%). Alternatively, conversion of 1 to vinyl triflate resin 4 followed by palladium-mediated couplings with aryl boronic