𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A convenient diastereoselective synthesis of β-aminodithioesters from mono-S-trimethylsilyl ketene dithioacetals.

✍ Scribed by Pierre Beslin; Philippe Marion

Book ID
108380379
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
164 KB
Volume
33
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The first synthesis of the ketene dithio
The first synthesis of the ketene dithioacetals from sugar lactones: a convenient access to 3-ulosonic acids
✍ Jacek Młynarski; Anna Banaszek 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 201 KB

Isomeric 2-deoxy aldonolactones undergo Horner-Emmons reactions with 2-[bis(2,2,2-trifluoroethoxy)phosphoryl] 1,3-dithiane, to give the corresponding ketene dithioacetals, which are the key intermediates in the synthesis of 3-deoxy-2-keto-aldonic adds.