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A convenient chemoenzymatic synthesis of (R)- and (S)-(chloromethyl)oxirane

✍ Scribed by Chen, Ching-Shih; Liu, Yeuk-Chuen; Marsella, Michael

Book ID
118068917
Publisher
Royal Society of Chemistry
Year
1990
Weight
380 KB
Volume
9
Category
Article
ISSN
1472-7781

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✍ Eirik Sundby; Jarle Holt; Anders Vik; Thorleif Anthonsen 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 106 KB

## Abstract Lipase‐catalyzed transesterifications and biological reductions were used to obtain the (__S__)‐enantiomers of 3‐chloro‐1‐(1,3‐dithian‐2‐yl)‐2‐propanol and 1‐(1,3‐dithian‐2‐yl)‐3‐fluoro‐2‐propanol and their (__R__)‐acetates. (__S__)‐3‐Chloro‐1‐(1,3‐dithian‐2‐yl)‐2‐propanol and (__R__)‐3