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A convenient approach to furan derivatives by I2-induced cyclisation of 2-alkenyl substituted 1,3-dicarbonyl compounds

โœ Scribed by R. Antonioletti; F. Bonadies; A. Scettri


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
202 KB
Volume
29
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


5-iodoalkyl-4,5-dihydrofurans

& 5-alXylldene-4,5-dihydrofurans 3 and 2,3,5_trisubstituted furans 4 are obtained through a simple sequence, involving, in the Key-step, a regio-and stereoselective iodoenoletherification of P-alXeny1 substituted i,3-dfcarbonyl compounds i.


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An easy approach to dihydrofurans by one
โœ Roberto Antonioletti; Giuliana Righi; Lia Oliveri; Paolo Bovicelli ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 59 KB

Dihydrofuran derivatives were obtained by a simple one-step procedure involving an easy epoxidation of 2-alkenyl-1,3-dicarbonyl compounds by dimethyldioxirane prepared in situ and a subsequent cyclisation under the same basic reaction conditions.