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A Convenient A2 + B3 Approach to Hyperbranched Poly(arylene oxindole)s

✍ Scribed by Mario Smet; Yu Fu; Xi Zhang; Etienne H. Schacht; Wim Dehaen

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
144 KB
Volume
26
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

Summary: We developed a facile approach to hyperbranched polymers by applying a superelectrophilic reaction within an A~2~ + B~3~ strategy. A significant reactivity difference between the intermediate and the starting material was utilized to avoid gelation in the A~2~ + B~3~ polymerization. A number of hyperbranched poly(arylene oxindole)s were achieved in a one‐step polymerization and characterized by NMR spectroscopy and gel permeation chromatography. Moreover, further modifications at the interior and exterior of the resulting polymers were explored as well.

Structure of the hyperbranched polymers produced using the A~2~ + B~3~ approach.

magnified imageStructure of the hyperbranched polymers produced using the A~2~ + B~3~ approach.

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