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A CONTRIBUTION TO THE TOTAL SYNTHESIS OF ALIZARIN 1 . SYNTHESIS OF 1,2-DIHYDROXY-9,10-ANTHRAQUINONE-9-C 14

โœ Scribed by WILLIAMS, D. LLOYD.; RONZIO, ANTHONY R.


Book ID
127217418
Publisher
American Chemical Society
Year
1953
Tongue
English
Weight
512 KB
Volume
18
Category
Article
ISSN
0022-3263

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First Synthesis of 9,10-Dimethoxy-2-meth
โœ Dipakranjan Mal; Sutapa Ray ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 243 KB

## Abstract The synthesis of 9,10โ€dimethoxyโ€2โ€methylโ€1,4โ€anthraquinone, an unusual quinone, was achieved in five steps from __p__โ€benzoquinone. A Kochiโ€“Anderson radical methylation features as the key step in the synthesis. The chemistry of a cyclopropaโ€1,4โ€anthracenedione is also described. (ยฉ Wil