Rate-limiting deprotonation of (arylsulf
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Maarten A. van Andel; Jan B. F. N. Engberts
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Article
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2010
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Elsevier Science
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English
⚖ 380 KB
## Abstract Kinetic data are reported for the water‐catalyzed hydrolysis of several (arylsulfonyl)‐methyl perchlorates in water and for the HMPA‐catalyzed decomposition of the same substrates in dichloromethane. Under both conditions, the reaction exhibits general base catalysis and the covalent pe