A computational study of the effect of the interaction potential for inelastic atom-molecule rotational scattering
β Scribed by D.W. Davies; S.J. Till
- Book ID
- 107744924
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 279 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0010-4655
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π SIMILAR VOLUMES
If the collisional ionization is chiefly due to energy transfer from the polar-molcculc rotation to an electron in a high Rydberg state of the atom, then theory predicts that the cross section averaged over a thermal distribution of rotational states should show step-like structure as a function of
A small proportion ( ~2%) of the ammonia molecules matrix-isolated in argon at concentrations between 0.5% and 4% rotate almost freely about their symmetry axis at ?'= 5 K. Interstitial ammonia defects are proposed as possible sources. The remainder of the molecules are immobile on the timescale of