A Computational and Conceptual DFT Approach to the Kinetics of Acid Zeolite Catalyzed Electrophilic Aromatic Substitution Reactions

Electrophilic aromatic substitution. 14.

Electrophilic aromatic substitution. 14. [1] A kinetic, NMR, and Raman study of the aluminum chloride-catalyzed reaction of p-toluene-sulfonyl chloride with benzene and toluene in dichloromethane

✍ Franklin P. DeHaan; Paul Y. Ahn; Carl R. Kemnitz; Steven K. Ma; Jim Na; Bimal R. 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 135 KB 👁 3 views

Vacuum line kinetic studies of the reaction of p-toluenesulfonyl chloride and benzene or toluene, using aluminum chloride as the catalyst and dichloromethane as the solvent were determined at 25ЊC by means of gas chromatography. The reaction is first-order in arene, tosyl chloride, and in AlCl 3 as