A compound with a tin-carbon double bond, bis(2,4,6-triisopropylphenyl)(fluorenylidene)stannane: aspects of its reactivity and X-ray structure of its dimer

Nucleophilic addition to C,C double bond

Nucleophilic addition to C,C double bonds. III. Chemical reactivity of 1endo, 4endo: 5exo, 8exo-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalen-10syn-ol and X-ray structure analysis of its p-nitrobenzoate

✍ Rolland A. Pfund; W. Bernd Schweizer; Camille Ganter 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 German ⚖ 400 KB

## Abstract The title compound **1** is a further example of an olefinic alcohol that undergoes ether formation under basic conditions **(→ 3)** although the double bond is not activated by an electron‐attracting group. This unusual reactivity is due to steric compression, which is increased in the