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A Comparison of the dielectric, acoustic, NMR and viscoelastic relaxation properties of supercooled liquids cyclic carbonates

✍ Scribed by A.K.M. Masood; R.A. Pethrick; A.J. Barlow; M.G. Kim; R.P. Plowiec; D. Barraclough; J.A. Ladd


Publisher
Elsevier Science
Year
1976
Weight
1023 KB
Volume
9
Category
Article
ISSN
0001-8716

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✦ Synopsis


Dielectric, acoustic, NMR and viscoelastic relaxation measurements are reported on four cyclic carbonates. These liquids are known to possess anomalies in their physicochemical properties and two of the molecules exhibit a marked tendency to supercool. Relaxation times are reported for certain of the systems and comparison between techniques suggests that anisotropy of rotation appears at the same temperature as the observed anomalies.


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Carbon-13 NMR. The analysis of the relax
✍ Nicole Platzer πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 544 KB

## Abstract Carbon‐13 relaxation times (__T__~1~) and nuclear Overhauser enhancements (Ξ·) have been measured for benzofuran and a series of its methyl derivatives. The contributions of dipolar (__T__~1~ ^DD^) and spin rotation (__T__~1~^SR^) mechanisms have both been determined. The temperature dep