## Abstract **Summary:** The dispersion polymerization of MMA in supercritical CO~2~ was successfully carried out utilizing the first non‐fluorous random copolymers composed of 3‐tris(trimethoxysilyl)propyl methacrylate and 2‐dimethylaminoethyl methacrylate, poly(SiMA‐__co__‐DMAEMA) as a stabilizer
✦ LIBER ✦
A Comparison of Modeling Approaches for Dispersion Homopolymerization of MMA and Styrene in Supercritical CO2
✍ Scribed by Iraís A. Quintero-Ortega; Gabriel Jaramillo-Soto; Pedro R. García-Morán; M. Luz Castellanos-Cárdenas; Gabriel Luna-Bárcenas; Eduardo Vivaldo-Lima
- Book ID
- 112147113
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 812 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1862-832X
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## Abstract A kinetic model is developed for the heterogeneous free‐radical copolymerization of vinylidene fluoride and hexafluoropropylene in supercritical CO~2~. The model accounts for polymerization in both the dispersed (polymer‐rich) phase and in the continuous (polymer‐free) supercritical pha