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A comparative theoretical study of 1,2-disubstituted ethylenes

✍ Scribed by J.B. Moffat


Book ID
119115787
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
351 KB
Volume
88
Category
Article
ISSN
0166-1280

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A facile synthesis of symmetrical 1,1-di
✍ Gerald L. Larson; David HernΓ‘ndez πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 201 KB

The reaction of ethyl trimethylsilylacetate with two equivalents of a Grignard reagent in ether followed by treatment with acid gives 1,1-disubstituted ethylenes in excellent yield. The use ofghydroxysilanes in the formation of olefins has been a useful reaction in organic chemistry since the first