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A comparative study of the structure of 2,3-dimethyl-2-butene

✍ Scribed by L. Doms; L. Van Den Enden; H.J. Geise

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
606 KB
Volume
94
Category
Article
ISSN
0022-2860

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πŸ“œ SIMILAR VOLUMES

Temperature dependence of the rate const
Temperature dependence of the rate constants of the reactions of oxygen atoms with trans-2-butene, cis-2-butene, 2-methylpropene, 2-methyl-2-butene, and 2,3-dimethyl-2-butene
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## Abstract The kinetics of the reactions of ground state oxygen atoms with __trans__‐2‐butene, __cis__‐2‐butene, 2‐methylpropene, 2‐methyl‐2‐butene, and 2,3‐dimethyl‐2‐butene was investigated in the temperature range 200 to 370K. In this range, the rate constants are (in units 10^βˆ’11^ cm^3^ s^βˆ’1^)

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It is shown that the fluorescence-excitation spectrum of tetramethylethylene (2,3dimethyl-2.butene) can be vibrationally resolved in a cold beam. A partial vibrational assignment, based on the observed analogy with the absorption spectrum of ethylened,, indicates that the fluorescence is excited by