A comparative study of the stereoselective addition of trimethylsilyl cyanide and diethylaluminum cyanide to chiral cyclic nitrones
β Scribed by Pedro Merino; Tomas Tejero; Julia Revuelta; Pilar Romero; Stefano Cicchi; Vanni Mannucci; Alberto Brandi; Andrea Goti
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 463 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0957-4166
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π SIMILAR VOLUMES
The use of a bimetallic titanium salen complex as a catalyst for the asymmetric addition of trimethylsilylcyanide to ketones is reported. The cyanohydrin trimethyisilyl ethers are obtained with enantiomeric excesses of up to 72% from reactions carried out at room temperature and atmospheric pressure
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