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A comparative study of the PK(II) and LSTH potential energy surfaces for the H3 system

โœ Scribed by Eli Pollak

Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
684 KB
Volume
18
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

Recent dynamical computations on the LSTH and PK(I1) potential energy surfaces are analyzed in terms of different properties of the surfaces. Differences in the bend level structure of resonances are found to be due to the weaker vibrational force constant at the saddle point of the LSTH surface. The importance of including van der Waals wells in the potential energy surface is demonstrated by analysis of quanta1 resonances in the collinear Mu + DZ reaction.

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