## Abstract The effects of the oxidation state, the ligand, and the solvent on structures and energetics of cationic iron complexes are investigated by means of electrosprayβionization mass spectrometry. Insights into the potentialβenergy surfaces of FeX^+^, FeX~2~^+^, and XFe(OCH~3~)^+^ ions (X =
A Comparative Study of Oxo-Ligand Effects in the Gas-Phase Chemistry of Atomic Lanthanide and Actinide Cations
β Scribed by Hans H. Cornehl; Ralf Wesendrup; Martin Diefenbach; Helmut Schwarz
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 960 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Molecular radical cations of oxazole (1) and isoxazole (2) dissociate by losing carbon monoxide or a hydrogen atom, respectively. These fragmentations were examined by use of tandem mass spectrometry, flash vacuum pyro- lysis and ab initiu molecular orbital calculations. A multi-step mechanism is pr
This paper reports a gas-phase study of ligand effects on the reactivity of the organometallic distonic ion Fe(p-benzyne) Γ . New organometallic distonic ions are generated by introducing a benzene ligand onto the metal center of Fe(p-benzyne) Γ . We were interested in whether the reactivity of the
Metal Β± ligand binding strength and selectivity result from antagonistic metal Β± ligand M Β± L attractions and ligand Β± ligand L Β± L repulsions. On the basis of quantum-mechanical (QM) calculations on lanthanide complexes, we show that this interplay determines the binding affinities in the gas phase
The mechanism of the reaction between H and CHrNOt, has been studied in a discharge flow system using electron paramagnetic resonance and modulated molecular beam mass spectrometry for the detection of reactants and products. Deuterium atoms have, in addition to CDfiOr, been used to support the prop