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A Comparative Study of Acrylamide Formation Induced by Microwave and Conventional Heating Methods

✍ Scribed by Y. Yuan; F. Chen; G.-H. Zhao; J. Liu; H.-X. Zhang; X.-S. Hu

Book ID
111405157
Publisher
Institute of Food Technologists
Year
2007
Tongue
English
Weight
136 KB
Volume
72
Category
Article
ISSN
0022-1147

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Baylis-Hillman acetates undergo a rapid S N 2 allylic substitution with ethyl (triphenyl phosphoranylidene) acetate under microwave irradiation to afford ethyl 5-aryl or alkyl-(E)-pent-4-enoates in high yields with high (E)-stereoselectivity. The reaction rates and yields are significantly improved