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A combined extraction and DFT study on the complexation of H3O+with a hexaarylbenzene-based receptor

✍ Scribed by Petr Toman; Emanuel Makrlík; Petr Vaňura; Václav Kašička; Rajendra Rathore

Publisher: Springer Vienna
Year: 2010
Tongue: English
Weight: 522 KB
Volume: 141
Category: Article
ISSN: 0026-9247
DOI: 10.1007/s00706-010-0313-5

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From extraction experiments and c-activity measurements, the extraction constant corresponding to the equilibrium H 3 O + (aq) + 1AE Na + (nb) ¡ 1AEH 3 O + (nb) + Na + (aq) taking place in the two-phase water-nitrobenzene system (1 = hexaethyl p-tert-butylcalix[6]arene hexaacetate; aq = aqueous phas