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A co-crystal of 2-methyl­benz­imidazole and ammonium octamolybdate

✍ Scribed by Feng, Si-Si ;Lu, Li-Ping ;Zhang, Hong-Mei ;Qin, Shi-Dong ;Li, Xue-Mei ;Zhu, Miao-Li


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
510 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, tetraammonium octamolybdate bis(2methylbenzimidazole), (NH 4 ) 4 [Mo 8 O 26 ]Á2C 8 H 8 N 2 , the crystal packing is stabilized by N-HÁ Á ÁO, N-HÁ Á ÁN and C-HÁ Á ÁO intra-and intermolecular hydrogen bonds, as well asstacking. The anion lies on an inversion center.


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Investigations of 2-substituted imidazol
✍ V. M. Stoyanov; M. M. El'chaninov; A. F. Pozharskii 📂 Article 📅 1991 🏛 Springer US 🌐 English ⚖ 416 KB

We have synthesized 2-(thienyl-2)imidazole and its N-methyl derivative. The latter product was obtained by nitration, bromination, acylation, and formylation, occurring as a rule on the thiophene ring. A general method for methylating 2-R-imidazoles with methyl iodide KOH--dimethoxy ethane is propos