A classical mean space charge model for solvation

✍ Scribed by S. Ehrenson

• Publisher: Elsevier Science
• Year: 1978
• Tongue: English
• Weight: 511 KB
• Volume: 56
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(78)89031-9

✦ Synopsis

Poiar contributions of non-nearest neighbor solvent to attenua:ion of intracavtty solute mteractions are modeled m terms of classica electrostatic theory. Bounds analysis su_eests linearizatton of the Poisson-Bohzmann equatton for the external field should usually be appropriate for generation of potent& and the effective dielectric constants they imply. * Research carried out at Brookhaven National Laboratory under contract with the U.S. Department of Energy and supported by its Division of Basic Energy Sctences. * Refs. [ I.21 survey the considerable body of gas phase work produced since the pioneering efforts of Kebarle [3] and Friedman [4] and co-workers_