A Claisen-Ireland rearrangement led to the formation of C-glycan derivatives. Azidonitration-reduction or dihydroxylation afforded gluco-and galacto-derived [3-C-glycosides. Subsequent deprotonation of bicyclic lactones 16 allowed the control of the newly created asymmetric centre.
β¦ LIBER β¦
A Claisen rearrangement route to the vineomycins
β Scribed by R.C. Cambie; M.G. Pausler; P.S. Rutledge; P.D. Woodgate
- Book ID
- 108382618
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 95 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
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