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A Circular Dichroism Approach to the Conformation of 1-Arylethylamino-Substituted 1,3,5-Triazine Derivatives

✍ Scribed by Anna Iuliano; Ilaria Voir; Piero Salvadori

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
274 KB
Volume
2000
Category
Article
ISSN
1434-193X

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✦ Synopsis

data of the optically pure 2-[(R)-1-(9-anthryl)ethylamino]-4-chloro-6-[(R)-1-(1-naphthyl)ethylamino]-1,3,5-triazine, 2-[(R)-1-(9-anthryl)ethylamino]-4,6-bis[(R)-1-(1-naphthyl)ethylamino]-1,3,5-triazine, 2,4-bis[(R)-1-(9-anthryl)ethylamino]-6-chloro-1,3,5-triazine are presented.

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Circular Dichroism of 9,10-Dihydrophenanthrene Derivatives Reveals both the Absolute Configuration and Conformation: A Novel Approach to Mislow's Helicity Rule
✍ Jacek GawroΕ„ski; Piotr Grycz; Marcin Kwit; Urszula Rychlewska πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 126 KB

The absolute configuration and the conformation of 9,10-trans-disubstituted 9,10-dihydrophenanthrenes, known chiral metabolites of phenanthrene-9,10-oxide, have been determined by circular dichroism. The absolute configuration assignment is based on the sign of the long-wavelength Cotton effect (A-b