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A chronopotentiometric study of fluoride ion discharge on various carbon materials

✍ Scribed by A.J. Calandra; C.M. Ferro; J. Thonstad

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
530 KB
Volume
37
Category
Article
ISSN
0013-4686

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✦ Synopsis

The electrochenucal hehavlour of fluonde Ion mscharge on graphite, pyrolytic graphite, carbon and ntreous carbon electrodes m pure cryobte and m pure so&urn fluonde melts was studied by applyins galvanostak pulses A correlation was found between the structure of the carbon elect&es bemg used and the number of transltlons which appeared Temperature change had a strong e&t on the translhon tunes observed at hgh antic potentmls on porous electrodes m pure sodmm fluondes, due to floodmg of pores The influence of the nature of the carbon on the Qscharge of oxide eons and fluonde eons Y dlscussed Key wordF anode effect, carbon structure, wettmg. temperature effect, reaction modal INTRODUCITON Expenmental studies of the mlhatlon of the anode effect on carbon anodes m sodnun fluonde and

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The effect of sluwsh bubble detachment and gas accumulation on the surface of carbon electrodes durmg fluonde eon discharge m molten fluondes was exammed m order to duxmgmsh Ween the effects of bubbles and film-type passlvlty For tis purpose a rea&on model mvolvmg the electrochenucal formatton of tw