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A Chiral Phenoxyamine Magnesium Catalyst for the Enantioselective Hydroamination/Cyclization of Aminoalkenes and Intermolecular Hydroamination of Vinyl Arenes

✍ Scribed by Dr. Xiaoming Zhang; Dr. Thomas J. Emge; Prof. Dr. Kai C. Hultzsch

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
1006 KB
Volume
51
Category
Article
ISSN
0044-8249

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[Ind2TiMe2]: A General Catalyst for the
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✍ Andreas Heutling; Frauke Pohlki; Sven Doye 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 296 KB 👁 2 views

## Abstract [Ind~2~TiMe~2~] (Ind=indenyl) is a highly active and general catalyst for the intermolecular hydroamination of alkynes. It catalyzes the reaction of primary aryl‐, __tert__‐alkyl‐, __sec__‐alkyl‐, and __n__‐alkylamines with internal and terminal alkynes. In the case of unsymmetrically s