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A chiral cobaltous complex with acetoneS-1,1′-binaphtyl-2,2′-diimine

✍ Scribed by I. V. Kalinina; D. N. Dybtsev; V. P. Fedin

Book ID: 106427671
Publisher: SP MAIK Nauka/Interperiodica
Year: 2008
Tongue: English
Weight: 202 KB
Volume: 49
Category: Article
ISSN: 0022-4766
DOI: 10.1007/s10947-008-0192-3

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## Abstract The migratory insertions of __cis__ or __trans__ olefins CH(X)CH(Me) (X = Ph, Br, or Et) into the metal–acyl bond of the complex [Pd(Me)(CO)(^i^Pr~2~dab)]^+^ [B{3,5‐(CF~3~)~2~C~6~H~3~}~4~]^−^ (1) (^i^Pr~2~dab = 1,4‐diisopropyl‐1,4‐diazabuta‐1,3‐diene = __N,N′__‐(ethane‐1,2‐diylidene)bi