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A Chemosensing Ensemble for Selective Carbonate Detection in Water Based on Metal–Ligand Interactions

✍ Scribed by Luigi Fabbrizzi; Antonella Leone; Angelo Taglietti

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
90 KB
Volume
113
Category
Article
ISSN
0044-8249

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A Chemosensing Ensemble for Selective Ca
A Chemosensing Ensemble for Selective Carbonate Detection in Water Based on Metal–Ligand Interactions
✍ Luigi Fabbrizzi; Antonella Leone; Angelo Taglietti 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 90 KB 👁 1 views

Displacement of the loosely encapsulated fluorescent indicator coumarine 343 (F) from a dicopper(II) cryptate enables the selective fluorimetric detection of the HCO3 (-) ion (A) in water (see scheme, •○=Cu(2+) ). The fluorophore is quenched when encapsulated, but displays its full emission when rel