𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A Chemical Study of Virginia Tobacco Flavour (Nicotiana Tabacum L.). I. Isolation and Synthesis of Two Bicyclodamascenones

✍ Scribed by Edouard Demole; Paul Enggist


Publisher
John Wiley and Sons
Year
1976
Tongue
German
Weight
403 KB
Volume
59
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Aged Virginia tobacco was steam‐distilled and the resulting condensate investigated by chromatographic methods. This allowed identification of the bicyclodamascenones A and B in a small subfraction from this condensate. Both these ketones, which are novel tobacco constituents, were also synthesized and a possible mechanism is proposed for their formation via acid‐catalysed cyclization of β‐damascenone (1).


📜 SIMILAR VOLUMES


A Chemical Study of Virginia Tobacco Fla
✍ Edouard Demole; Paul Enggist 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 German ⚖ 438 KB 👁 1 views

## Abstract Gas liquid chromatography allowed isolation of the novel __cis__‐2‐isopropenyl‐8‐methyl‐1,2,3,4‐tetrahydro‐1‐naphthalenol (**A**) and its dehydration product, 3‐isopropenyl‐5‐methyl‐1,2‐dihydronaphthalene (**B**), from two small subfractions of __Virginia__ tobacco condensate. Both thes

A Chemical Study of Burley Tobacco Flavo
✍ E. Demole; Mrs C. Demole; D. Berthet 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 German ⚖ 396 KB 👁 1 views

## Abstract Two novel constituents of __Burley__ tobacco condensate were shown to be 5‐(4‐methyl‐2‐furyl)‐6‐methylheptan‐2‐one (__solanofuran__, **4**) and 3,4,7‐trimethyl‐1,6‐dioxa‐spiro[4.5]‐dec‐3‐en‐2‐one (__spiroxabovolide__, **6**). These structures were deduced from spectral data and confirme

A Chemical Study of Burley Tobacco Flavo
✍ E. Demole; (Mrs) C. Demole; D. Berthet 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 184 KB 👁 2 views

The principal axes of the 50%-thermal vibration ellipsoids for C-and 0-atoms vary between 0.18 and 0.35 8. A qualitative impression of the relative orientation of the ellipsoids can be obtained from the stereoscopic drawing of the molecule in Fig. 2 ) , which also shows the overall conformation of