A set of non-lmear cqustlons LS given winch solves the stationary Schrodmgcr equalion III terms of a known subproblem. An ItemlIve solution of the equations ylclds the degenerate version of Raylegh-SchrBdmgcr perturbation theory, but olhcr approxunatlon schemes, as well as a purely numerIca solullon
A change of variable for the perturbation parameter in rayleigh–Schrödinger perturbation theory
✍ Scribed by A. T. Amos
- Publisher
- John Wiley and Sons
- Year
- 1972
- Tongue
- English
- Weight
- 273 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0020-7608
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A diagammatic,interprct~tion of the formal (i.e.; without second quantization ~ormalismj quasi-degenerate Rayleigh-Sciuiidinger perturbation theory with non-hem+ian model hamiltonian is suggested. fn this appro&. : the diagrammatic expressions for the Bloch wave operator U as well as for the model
## Abstract Several useful “redefined zero‐order Hamiltonian” variants of the Rayleigh–Schrödinger perturbation theory are derived by exploiting the freedom of choice for the orthogonality integral between zero‐ and first‐order wavefunctions. It is found that the more common Hamiltonian repartition