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A centrifugal sudden distorted wave study of the reaction Cl + HCl → ClH + Cl: product rotational distributions

✍ Scribed by George C. Schatz; B. Amaee; J.N.L. Connor


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
460 KB
Volume
132
Category
Article
ISSN
0009-2614

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✦ Synopsis


Accurate quantum cross sections for the Cl + HCl + QH + Cl reaction using an extended LEPS potentialenergy surface and the centrifugal sudden distorted wave method are presented, which indicate that the product HCl is highly rotationally excited (receiving 40-50% of the available energy) and that the shape of the product rotational distribution is nearly independent of reagent rotational state.