A Catalytic Hydrogen Wave of the Osmium-Cysteine System
β Scribed by Mikio Kawasaki; Teiji Kakizaki; Wenzhi Hu; Kazuhiro Toyota; Kiyoshi Hasebe
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 71 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1040-0397
No coin nor oath required. For personal study only.
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## Abstract A mechanism for the oxidation of cysteine by hydrogen peroxide has been proposed by Luo et al. (__J Pharm Sci__, 2005, 94, 304β316): rapid equilibrium to form cysteinate (CS^β^), followed by irreversible oxidation of CS^β^ by H~2~O~2~ to give cysteine sulfenic acid (CSOH), and nucleophi