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A catalytic asymmetric synthesis of cis-decalin derivatives via π-allylpalladium intermediates

✍ Scribed by Toshiyasu Takemoto; Yuji Nishikimi; Mikiko Sodeoka; Masakatsu Shibasaki

Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
141 KB
Volume
33
Category
Article
ISSN
0040-4039

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A catalytic asymmetric synthesis of a versatile intermediate for phorbol derivatives
✍ Hideaki Sato; Yun Sik Kim; Masakatsu Shibasaki 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 242 KB

A catalytic asynunetric cyclopropanation of enol silyl ether 9 gave the laeton¢ 3 in up to 78% e¢. The lacton¢ 3 was then Iransformcd into 2, potentially a very versatile intermediate for phorbol analogs, using an inu'amol~cular nitrile oxide cycloaddition as a key step.