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A Catalytic Approach for Cationic Living Polymerization: Sc(OTf) 3 -Catalyzed Ring-Opening Polymerization of Lactones

✍ Scribed by Nomura, Nobuyoshi; Taira, Atsuko; Tomioka, Takashi; Okada, Masahiko


Book ID
120337212
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
107 KB
Volume
33
Category
Article
ISSN
0024-9297

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✍ Kiyoko Yoshida; Fumio Sanda; Takeshi Endo πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 167 KB πŸ‘ 3 views

A spiro orthoester having an ester moiety, 2-acetoxymethyl-1,4,6trioxaspiro[4.6]undecane (4) was synthesized, and its cationic polymerization and depolymerization of the obtained polymer (5) were carried out. The monomer 4 underwent cationic polymerization with a cationic catalyst to afford the corr