A case of non-axial symmetry of lanthanide NMR dipolar shifts as related to the conformational uses of the lanthanide probe method

Use of lanthanide shift reagents to prob

Use of lanthanide shift reagents to probe the conformation of fatty acids in solution by 13C NMR

✍ Miquel Pons; Dennis Chapman 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 460 KB

The conformational analysis of short polymer chains involves the use of statistical models, and their predictions must be checked against experimental information. Ytterbium-induced shifts in the "C NMR spectra of fatty acids provide a non-perturbing, straightforward method of simultaneously obtaini